Complexation of mercury by dissolved organic matter in surface waters of Galveston Bay, Texas   总被引：3，自引：0，他引：3  

Seunghee Han  Gary A. Gill  Ronald D. Lehman  Key-Young Choe 《Marine Chemistry》2006,98(2-4):156-166

The chemical speciation of dissolved mercury in surface waters of Galveston Bay was determined using the concentrations of mercury-complexing ligands and conditional stability constants of mercury-ligand complexes. Two classes of natural ligands associated with dissolved organic matter were determined by a competitive ligand exchange-solvent solvent extraction (CLE-SSE) method: a strong class (L_s), ranging from 19 to 93 pM with an average conditional stability constant (K_HgLs) of 10²⁸, and a weak class (L_w) ranging from 1.4 to 9.8 nM with an average K_HgLs of 10²³. The range of conditional stability constants between mercury and natural ligands suggested that sulfides and thiolates are important binding sites for dissolved mercury in estuarine waters. A positive correlation between the estuarine distribution of dissolved glutathione and that of mercury-complexing ligands supported this suggestion. Thermodynamic equilibrium modeling using stability constants for HgL, HgCl_x, Hg(OH)_x, and HgCl(OH) and concentrations of each ligand demonstrated that almost all of the dissolved mercury (> 99%) in Galveston Bay was complexed by natural ligands associated with dissolved organic matter. The importance of low concentrations of high-affinity ligands that may originate in the biological system (i.e., glutathione and phytochelatin) suggests that the greater portion of bulk dissolved organic matter may not be important for mercury complexation in estuarine surface waters.  相似文献   

离子色谱分析在黄土和粉尘研究中的应用   总被引：1，自引：0，他引：1  

王丹  屈文军  张小曳  严立文  曹国良 《海洋地质与第四纪地质》2005,25(1):113-118

黄土中存在着大量的碱金属及碱土金属，以往的测试方法多为原子吸收和ICP—MS，离子色谱法在测试黄土样品的碱金属和碱土金属元素含量中应用不多。将黄土地质标准样品进行消解后用离子色谱进行测试，测试效果良好，重复测试的相对标准偏差小于5％，与推荐值的相对误差小于5％，准确度和精密度符舍相关的质量控制要求。本实验方法测试的离子含量都在仪器响应呈线性的最佳测试范围之内，标准曲线经回归后相关系数均达到0．9999。黄土样品的分析结果与粉尘气溶胶样品的离子分析结果对比表明，此方法对于探讨粉尘起源以及沙尘暴天气的研究具有重要意义。  相似文献   

Efficacy of beach dewatering — Alassio,Italy     

Dan Bowman  Serena Ferri  Enzo Pranzini 《Coastal Engineering》2007

The goal of this study is to estimate the efficiency of dewatering operations in Alassio Beach, north Italy by following an integrated approach which included beach volume calculations, daily mapping of the shoreline position, examination of specific beach widening events and daily comparisons of morphodynamic characteristics of the drained beach versus a control section which included wave run-up, bar patterns, rip migration, evolution of the berm and cusp morphology.  相似文献   

日照港和邻近锚地及其入境船舶压舱水中浮游植物群集结构的特征   总被引：1，自引：1，他引：1  

李伟才  孙军  王丹  贾俊涛  雷质文  王小冬 《海洋科学》2006,30(12):52-57

根据2003年10月到2004年3月间日照港和邻近锚地水域及其船舶压舱水中的浮游植物调查资料,对浮游植物的群集结构和压舱水对其影响进行了初步研究。结果表明,日照港的浮游植物群集主要由温带沿岸性物种组成,以硅藻为主,还有少量的甲藻。对比船舶压舱水中浮游植物群集发现:压舱水中浮游植物群集和本地群集结构有很大的差异,有害物种在压舱水中所占的比例较高。  相似文献   

絮凝法强化大生活用海水一级处理研究   总被引：3，自引：0，他引：3  

张雨山  王静  寇希元  单科 《海洋技术学报》2002,21(4):57-60

研究了无机絮凝剂石灰、硫酸铝、聚合氯化铝、聚合硫酸铁和氯化铁单独使用及其与有机高分子絮凝剂聚丙烯酰胺（PAM）配合使用时强化大生活用海水一级处理的效果，结果表明，无机絮凝剂与有机絮凝剂配合使用时有很好的强化效果，COD去除率最高达61%，且对SS和BOD也有一定的去除效果。  相似文献   

四种重金属对刺参幼参的急性致毒效应   总被引：1，自引：0，他引：1  

孙振兴  陈书秀  陈静  高洪梅  李丹 《海洋通报》2007,26(5):80-85

采用静水试验法,在水温18.5℃~20℃的条件下,用Cu2 ,Zn2 ,Cd2 和Cr6 四种重金属对刺参幼参进行了单一急性毒性试验。结果表明:Cu2 对刺参幼参的24h,48h,72h和96hLC50分别为0.299,0.176,0.133和0.120mg/L;Zn2 的24h,48h,72h和96hLC50分别为6.700,3.624,2.577和1.951mg/L;Cd2 的24h,48h和72hLC50分别为4.246,2.588和2.137mg/L;Cr6 的24h,48h和72hLC50分别为31.974,7.499和3.808mg/L;Cu2 ,Zn2 ,Cd2 和Cr6 对刺参幼参的安全浓度分别为0.018,0.362,0.259和0.750mg/L。四种重金属对刺参幼参的毒性大小依次为Cu2 >Cd2 >Zn2 >Cr6 。  相似文献   

Study on the connectivity of heavy oil reservoirs by ultraviolet spectrum technique in the western part of the QHD32-6 oilfield     

Yaohui Xu  Dan Chen 《中国地球化学学报》2008,27(3):306-309

As a new method, the ultraviolet spectrum technique is applied to studying the connectivity of biode-gradable heavy oil reservoirs. The similarity of crude oils can be judged according to the extinction coefficient （E） because aromatic hydrocarbons and non-hydrocarbons have conjugated bonds and obvious absorption in the ultraviolet range, and different materials have different characteristics and additives. The relationship diagram is made in terms of the extinction coefficients （E） of the samples by taking E as the Y-axis and wavelength as the X-axis. The connectivity of oil reservoirs is estimated according to the curve positions and characteristic fingerprints of the sampies. The connectivity of part of the reservoirs in the western part of the QHD32-6 oilfield was studied with this method. The results showed that the connectivity of samples from wells F7 and F8 in the Nm-2 oil reservoir zone is good, that of samples from wells F17 and F20 in the Nm-1 oil reservoir zone also is good, and that of samples from wells F17, F19, and F20 is poor.  相似文献   

基于GIS的北京城市形态研究   总被引：1，自引：0，他引：1  

吴琼  HU Dan  李宏卿  YANG Guo-dong  何永  WANG Bi-hui  刘莉 《世界地质》2008,27(2)

经典的城市形态理论包括同心圆理论、扇形理论和多核心理论.利用2002年北京市土地利用图,采用GIS缓冲区分析的方法,分析了北京市各功能用地的方向特征和圈层特征.结果表明:北京市的土地利用体现了明显的圈层特征,同时各类功能用地在各方向的分布又明显受到了河流、交通干道和工业区等地理要素的影响.北京没有形成城市总体规划的多中心布局,第一道绿化隔离地区中绿地面积没有明显高出其他地区,基本上已经失去了中心城区和边缘集团隔离开的功能.总体上,北京城市空间形态主要是同心圆和扇形的结合,更接近同心圆理论和扇形理论的混合形式.  相似文献   

地质和岩土工程光纤传感监测技术综述   总被引：3，自引：0，他引：3  

隋海波  施斌  张丹  王宝军  魏广庆  朴春德 《工程地质学报》2008,16(1):135-143

光纤传感器与常规传感器相比具有很大的优越性,已经成为地质和岩土工程监测领域中的研究热点。本文介绍了光纤传感监测系统的种类、基本测量原理和目前国内外的研究发展状况,并对各种传感技术的性能和特点进行了比较,指出了光纤传感监测技术应用于地质和岩土工程监测尚需研究的相关课题。  相似文献   

Multiple Volcanic Episodes of Flood Basalts Caused by Underplating     

ZHU Dan  XU Yigang  SONG Xieyang  HU Ruizhong 《矿物岩石地球化学通报》2008,27(Z1)

Most Large igneous provinces (LIPs) are emplaced within <10 Ma, with a main pulse of the magmatism in<1 Ma[1]. For example, the Siberian Traps [2] and the Deccan Traps [3] were probably erupted within one million years. Many events, such as the Columbia River event, feature a single pulse of magmatism, followed by a protrac-ted period of magmatism at a much lower rate that is linked to a plume tail[4].  相似文献